Chemische Cluster Von Skelettnummern Zu Kappenindizes
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Chemische Cluster Von Skelettnummern Zu Kappenindizes

Chemische Cluster Von Skelettnummern Zu Kappenindizes


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About the Book

Die jüngste Entdeckung der Skelettnummern ermöglichte es, Hunderte von chemischen Clustern zu analysieren und zu kategorisieren. Dabei wurde auch der Kategorisierungsparameter K*= DzCy entdeckt, wobei z+y=n (die Gesamtzahl der Skelettelemente) ist. In konventionellen Clustern können die Skelettelemente in einem Cluster in zwei Schalen aufgeteilt werden, nämlich in die D-Schale und die C-Schale. Die D-Schale folgt der 14n-Kappungsreihe, während die C-Schale der 12n-Kappungsreihe folgt. Bei genauer Betrachtung und Analyse der Clusterreihen wurde eine Gleichung zur Bestimmung der Clustervalenz-Elektronen entwickelt. Die Gleichung lautet: VE=14z+2+12y für Übergangsmetallcluster. Da VE=VF ist und aus den Clusterformeln berechnet werden kann, lassen sich die Werte von z und y leicht als VF= 14z+2+12y berechnen. Tatsächlich können diese beiden Gleichungen vereinfacht werden, um eine viel einfachere Gleichung VF-12n=2z+2 zu erhalten. Wenn man also VF und n kennt, kann man den Wert von z und anschließend den von y leicht ermitteln. Somit kann K*=DzCy ohne Verwendung von Skelettzahlen abgeleitet werden. Aus K* lassen sich die Clusterzahl K und die Valenzelektronen des Clusters ableiten und isomere Formen konstruieren.


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Product Details
  • ISBN-13: 9786208047832
  • Publisher: KS Omniscriptum Publishing
  • Binding: Paperback
  • Language: German
  • Returnable: N
  • Weight: 363 gr
  • ISBN-10: 6208047838
  • Publisher Date: 24 Sep 2024
  • Height: 229 mm
  • No of Pages: 244
  • Spine Width: 14 mm
  • Width: 152 mm


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