Chapter 1- Intramolecular Electrostatic Interacations
1.1 - Introduction
1.2- Intramolecular Electrostatic Interactions
References
Chapter 2- Anomeric Effects
2.1-Anomeric effect and related stereoelectronic effects
2.2-Exo-anomeric effect
2.3-Generalized anomeric effect
2.4-Anomeric effect in systems O-C-N
2.5-Gauche effect
References
Chapter 3- Acid Catalyzed Hydrolysis of Glycosides
3.1- Oxocarbenium ion
3.2- The acid-catalyzed hydrolysis of glycosides
3.3- The acid-catalyzed hydrolysis of glycopyranosides
3.4- The acid-catalyzed hydrolysis of glycofuranosides
3.5- Some recent developments regarding the mechanism of glycoside hydrolysis
3.6- Acetolysis of glycosides
References
Chapter 4- Conformation and Chemistry of Oxocarbenium Ion
4.1- Conformation and Chemistry of Oxocarbenium Ion
References
Chapter 5- Glycosylation
5.1- Armed-disarmed concept in the synthesis of glycosidic bond
5.2- Stereoelectronic effects of substituents. Polyhydroxylated piperidines and sugars
5.3- Glycosylation reactions with conformationally armed donors
5.4- Superarmed glycosyl donors in glycosylation reactions
5.5-Regio- and stereoselectivity of glycosylation
5.6- Proton-catalyzed addition of alcohols to glycals: glycals as glycosyl donors
References
Chapter 6- Stereoelectronic Effects in Nucleosides and Nucleotides
6.1- Stereoelectronic effects in nucleosides and nucleotides
References
Chapter 7- Free Radical Cyclizations
7.1- Free-radical cyclizations
References
Chapter 8- Sulfones, Olefins, Nitrones, Glycosidic Bond, and Norrish-Young Photocyclization
8.1- Carbohydrate sulfones
8.2- Michael addition to vinyl sulfones
8.3- Glycosyl sulfones
8.4- Strecker reaction
8.5- Mercuration of carbohydrate olefins
8.6- 1,3-Dipolar cycloaddition of chiral N-(alkoxyalkyl)nitrones
8.7- Synthesis of glycosides by reduction of sugar orthoesters
8.8- Reductive cleavage of glycosidic bond
8.9- Carbohydrate degradation by oxygen
8.10 Norrish-Young photocyclization
References
Author Index
Subject Index
