Sintesi solvotermica di Li4C10H2O8 per anodi LIB ad alte prestazioni
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Sintesi solvotermica di Li4C10H2O8 per anodi LIB ad alte prestazioni

Sintesi solvotermica di Li4C10H2O8 per anodi LIB ad alte prestazioni


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About the Book

Tra tutti gli elettrodi a base inorganica per le batterie agli ioni di litio, quelli a base organica si distinguono per essere candidati alla futura generazione di materiali sostenibili ed ecologici. Il sale di tetralitio 1,2,4,5-benzenetracarbossilato (Li4C10H2O8) è stato preparato attraverso una semplice reazione di scambio ionico e utilizzato come anodo per batterie agli ioni di litio. Sono stati condotti due diversi trattamenti della reazione per confrontare le diverse morfologie e le prestazioni elettrochimiche. È stato dimostrato che il tetralitio 1,2,4,5-benzenetracarbossilato (Li4BTC-S) trattato solvotermicamente presenta una morfologia e prestazioni elettrochimiche migliori, soprattutto per quanto riguarda l'alta densità di corrente. I nanostrati uniformi e ben ordinati di Li4BTC-S presentano migliori prestazioni elettrochimiche grazie ai siti porosi tra ciascun foglio, che si ritiene riducano il percorso di diffusione dello ione Li-. Sono stati eseguiti calcoli DFT per comprendere un nuovo meccanismo di accumulo di Li4BTC-S. Sono state scoperte capacità in eccesso fino a 1016 mAh g-1 durante un paio di primi cicli iniziali e si sono stabilizzate a 600,62 mAh g-1 dopo 100 cicli. La Li4BTC-S rivela migliori prestazioni in termini di densità di corrente fino a 8 A g-1 e buona recuperabilità.


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Product Details
  • ISBN-13: 9786205689622
  • Publisher: KS Omniscriptum Publishing
  • Publisher Imprint: Edizioni Sapienza
  • Height: 229 mm
  • No of Pages: 52
  • Spine Width: 3 mm
  • Width: 152 mm
  • ISBN-10: 6205689626
  • Publisher Date: 20 Feb 2023
  • Binding: Paperback
  • Language: Italian
  • Returnable: N
  • Weight: 141 gr


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