Sintesis de Hidantoinas 5-Sustituidas by Gustavo Lafuente
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Sintesis de Hidantoinas 5-Sustituidas

Sintesis de Hidantoinas 5-Sustituidas


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About the Book

El objetivo del presente trabajo es estudiar la síntesis y reactividad de hidantoínas 5-sustituidas. Este tipo de hidantoínas son importantes intermedios en la producción industrial de aminoácidos. El trabajo se divide en dos partes. Por un lado en la síntesis de 5-aril-hidantoínas y por otro en la síntesis y reactividad de 5-metilenhidantoínas. La primera estrategia se ha realizado mediante una alquilación de Friedel-Crafts. Este tipo de reacciones se pueden llevar a cabo a partir de urea, ácido glioxílico y el compuesto aromático one-pot. Otra posibilidad es el uso de un derivado de hidantoína como es el caso de 5-clorohidantoína o 5-bromohidantoína. En la segunda estrategia se ha introducido un grupo metileno en posición 5 de la hidantoína. Este grupo sirve de intermedio sintético para obtener un gran número de moléculas mediante reacciones tipo Michael, cicloadiciones, reacciones de Heck, etc.


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Product Details
  • ISBN-13: 9783846574454
  • Publisher: Eae Editorial Academia Espanola
  • Publisher Imprint: Eae Editorial Academia Espanola
  • Height: 229 mm
  • No of Pages: 320
  • Series Title: Spanish
  • Weight: 521 gr
  • ISBN-10: 3846574457
  • Publisher Date: 06 Jul 2012
  • Binding: Paperback
  • Language: Spanish
  • Returnable: N
  • Spine Width: 18 mm
  • Width: 152 mm


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