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Thermodynamics for Chemists, Physicists and Engineers

Thermodynamics for Chemists, Physicists and Engineers


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About the Book

Dedication.- Preface.- Part I: Foundations of thermodynamics.- 1 Historical introduction.- 2 Basic concepts and definitions.- 2.1 Concept of thermodynamic equilibrium.- 2.2 Extensive parameters of state.- 2.3 Intensive parameters of state.- 2.4 Equations of state.- Exercises.- 3 Internal energy, work and heat.- 3.1 First law of thermodynamics.- 3.2 Isochoric process.- 3.3 Isobaric process.- 3.4 Adiabatic process.- 3.5 Isothermal process.- 3.6 Evaporation of liquids.- 3.7 Chemical reaction.- Exercises.- 4 Entropy and irreversibility of thermodynamic processes.- 4.1 Second law of thermodynamics.- 4.2 Conditions of thermodynamic equilibrium.- 4.3 Entropy as a function of state parameters.- 4.4 Changes in entropy in reversible processes.- 4.5 Heat devices.- 4.6 Changes in entropy in irreversible processes.- 4.7 Third law of thermodynamics.- Exercises.- 5 Thermodynamic potentials.- 5.1 Legendre transformation of the internal energy and entropy.- 5.2 Natural variables.- 5.3 Free-energy minimum principle.- 5.4 Examples of application of thermodynamic potentials.- 5.5 Intrinsic stability of a system.- Exercises.- Part II: Phase transitions.- 6 Phase transitions in pure substances.- 6.1 Concept of phase.- 6.2 Classification of phase transitions.- 6.3 Conditions of phase coexistence.- 6.4 Phase diagrams.- 6.5 Two-phase coexistence lines.- 6.6 Liquid-vapour two-phase region.- 6.7 Van der Waals equation of state.- Exercises.- 7 Mixtures.- 7.1 Basic concepts and relations.- 7.2 Intrinsic stability of a mixture.- 7.3 Partial molar quantities and functions of mixing.- 7.4 Mixture of ideal gases.- 7.5 Ideal mixture.- 7.6 Real mixtures.- 7.7 Phase rule.- Exercises.- 8 Phase equilibrium in ideal mixtures.- 8.1 Liquid-gas equilibrium.- 8.2 Liquid-solid equilibrium.- 8.3 Osmotic equilibrium.- 8.4 Colligative properties.- Exercises.- 9 Phase equilibrium in real mixtures.- 9.1 Liquid-vapour equilibrium.- 9.2 Liquid solutions with miscibility gap.- 9.3 Liquid-vapour equilibrium in presence of miscibility gap.- 9.4 Liquid-solid equilibrium and solid solutions.- Exercises.- Part III: Chemical thermodynamics.- 10 Systems with chemical reactions.- 10.1 Condition of chemical equilibrium.- 10.2 Effect of external perturbation on chemical equilibrium.- 10.3 Law of mass action for ideal gases.- 10.4 Thermochemistry.- 10.5 Phase rule for chemical systems.- Exercises.- 11 Electrochemical systems.- 11.1 Electrolyte solutions.- 11.2 Aqueous solutions of acids and bases.- 11.3 Electrochemical cells.- 11.4 Reversible cell.- Exercises.- Solutions .- References.- Index.


About the Author:

Robert Holyst (1963) is a professor at the Institute of Physical Chemistry Polish Academy of Sciences. He specializes in statistical physics, physical chemistry, biologistics and soft matter physics. He has published 182 papers and 2 books. He presented his works at multiple universities/institutes, e.g. Harvard, MIT, University of Chicago, ESPCI-Paris, ENS-Paris, several Max Planck Institutes, University of Tokyo, Oxford and Cambridge. He has over 17 years experience in teaching thermodynamics for undergraduate students.

Andrzej Poniewierski (1951), professor at the Institute of Physical Chemistry Polish Academy of Sciences; published 53 papers and two books, specializes in soft matter and statistical physics, liquid crystals and applications of density functional theory to complex fluids. He has also taught thermodynamics for undergraduate students for several years.


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Product Details
  • ISBN-13: 9789401783040
  • Publisher: Springer
  • Publisher Imprint: Springer
  • Edition: 2012 ed.
  • Language: English
  • Returnable: N
  • Spine Width: 19 mm
  • Width: 156 mm
  • ISBN-10: 9401783047
  • Publisher Date: 09 Aug 2014
  • Binding: Paperback
  • Height: 234 mm
  • No of Pages: 344
  • Series Title: English
  • Weight: 557 gr


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